Extreme oxygen and magnesium isotopic anomalies in presolar spinel grains from the Murray carbonaceous meteorite.

Gyngard F., Morgand A., Nittler L. R., Stadermann F. J., and Zinner E. (2009)
Lunar & Planet. Sci. 40, Abstract #1386.


ABSTRACT

Presolar spinel grains have been identified in several meteorites by their anomalous O isotopic compositions and fall into the four previously defined oxide groups. The majority of these grains, in groups 1-3, are believed to originate in various types of red giant (RGB) and asymptotic giant branch (AGB) stars, while the enigmatic Group 4 grains, characterized by 18O excesses, have been hypothesized to be of a supernova (SN) origin. Magnesium-Al spinel grains allow for relatively precise determination of Mg isotopic ratios, in contrast to previous Mg isotopic measurements in presolar SiC, corundum, and graphite, where Mg is a minor element. Most of the previously measured spinel grains' Mg isotopic compositions, characterized by modest enrichments of 25Mg up to ~150‰, can be explained by nucleosynthetic processes. However, several grains have been reported whose extreme Mg compositions are difficult to explain with current AGB models. We report here O isotopic data on 40 new spinel grains from the Murray carbonaceous (CM2) chondrite and Mg isotopic data of the 28 grains remaining after O isotopic analysis. Several grains have very large 25,26Mg anomalies, and one grain has the largest 17O/16O ratio ever observed.


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